Hi all!
Whatever it is, we will continue.
I need to remind myself and everyone..
Time frame is about 5 years.
While searching in patent databases, I came across several interesting patents on which promising experiments (at that time
) were carried out.
Low temperature catalytic thermolysis of water - production of hydrogen without electrolysis.
Process for producing hydrogen:https://patents.google.com/patent/SU807584A1/en?oq=SU807584A1Amount of Calcium Oxide Powder: 200 grams
The amount of water vapor present in the reactor: 50 grams
Pressure in the reactor: 0,87 atmospheres
(But about the pressure in this patent, it is not entirely clear. If you study other patents of this author, there are indications that in the process of preparing "calcium hydroxide" he lowered the pressure to 0.01 atmospheres)
Method for hydrogen production:https://patents.google.com/patent/GEP20074038B/en?oq=GEP20074038BAbstract:
A method comprises heating water vapor together with the catalyst at pressure 8,0-10,0 atm. The received mix is cooled during (3-5)х10-3sec. up to temperature 70,0-80,00С and simultaneously with it pressure is lower up to 0,5-0,7atm. Then by means of addition water vapor hydrogen is isolated and process is repeated.
Amount of Calcium Oxide Powder: 200 grams
Pressure inside the reactor: 0,5 - 10 atmospheres
Temperature 70 - 400 Celsius
Water 100 ml
Amount of hydrogen: 0.66 - 0.72 % from the water, or 0.66 - 0.72 grams hydrogen, 7788 cubic centimeters of gas, 84 kilojoules if burned.
Thermolysis of water in contact with zeolite masses:https://patents.google.com/patent/US3963830A/en?oq=US3963830Catalytical process for obtaining hydrogen from water:https://patents.google.com/patent/RO95468B1/en?oq=RO95468B1About zeolite:https://www.youtube.com/watch?v=x2DSI-v9k8cQuantum field as a hypothetical energy source for reversible chemistry:https://digital.sandiego.edu/cgi/viewcontent.cgi?article=1001&context=phys-faculty..when a real molecule is placed between such plates, its energy levels behave in strange ways. And this latest paper demonstrates that with a photochemical rearrangement – the reaction rates change completely depending on whether or not the starting material is confined in the right sort of space, and they change exactly as the cavity is tuned more closely to the absorption taking place. In effect, the molecule is now part of a completely new system (molecule-plus-cavity), and this new system has different energy levels – and can do different chemistry.
The photochemistry shown is not exciting per se, but the fact that it can be altered just by putting the molecule in a very tiny box is exciting indeed:...
https://blogs.sciencemag.org/pipeline/archives/2012/09/14/chemistry_in_the_quantum_vacuum_no_reallyPossible Role of Oxides in the Fleischmann-Pons Effect:Jean-Paul Biberian, Iraj Parchamazad and Melvin H. Miles
Aix-Marseille University, France, University of LaVerne, LaVerne, CA, U.S.A.,
https://citeseerx.ist.psu.edu/viewdoc/summary?doi=10.1.1.380.2981Method for producing oxygen and hydrogen from waterhttps://patents.google.com/patent/US4278650AWater is fed into a high temperature pressurized vessel containing hydrated large-port mordenite having a high Si/Al ratio and containing a cation that is selected from a specified group of metals and that is in its highest oxidation state. The high temperature causes an endothermic redox reaction that produces oxygen gas and, as a solid reaction product, a large-port mordenite wherein the metal cation is in a lower oxidation state. The solid reaction product is passed through a heat exchanger, where it is cooled and then into a second pressurized reaction vessel at low temperature whereby there occurs an exothermic redox reaction that produces hydrogen gas and which oxidizes the cation back to its highest oxidation state. The large-port mordenite generated in the second reaction vessel is passed through the heat exchanger, where it is heated, and then back into the first reaction vessel for recycling. Pressurization is employed in the reaction vessels to prevent dehydration and this, together with the composition of the mordenite and the use of the heat exchanger, provides high thermal efficiency.
Dynamical Casimir effect in metamaterial converts vacuum fluctuations into real photons:https://phys.org/news/2013-03-nihilo-dynamical-casimir-effect-metamaterial.htmlZero-Point Energy extraction:https://www.youtube.com/watch?v=oLEJTaY307EUnlocking Zero-Point Energy:https://www.youtube.com/watch?v=2tGRhTXKh8AZero-Point Energy Demystified:https://www.youtube.com/watch?v=Rh898Yr5YZ8Zero Point Energy | Dr. Thorsten Ludwig:https://www.youtube.com/watch?v=bCvbqMGPpa8
Not only water, but carbon dioxide:https://patents.google.com/patent/SU1011511A1/enMethod of catalytic decomposition of water:https://patents.google.com/patent/US7357912B2/enPreferable solid acid catalysts and the solid base catalysts are particles having 1 to 50 μm. The main component of the solid acid catalysts is silicon acids, and the main component of the solid base catalysts is at least one of alkali metal compounds and alkaline earth metal compounds. Preferable silicon oxides are alumino-silicates. The solid base catalyst contains at least one oxide of K, Mg, and Ca. The temperature of water is 130° C. or higher.
alumino-silicates - same as zeolite
Thermolysis of water in contact with zeolite masses:https://patents.google.com/patent/US3963830A/enNear the RO95468B1 patent.
Method for producing oxygen and hydrogen from waterhttps://patents.google.com/patent/US4278650A/endynamic version
Catalyst for production of hydrogen or oxygen:https://patents.google.com/patent/JPH10263397A/enProduction of gaseous hydrogen by direct thermal decomposition of water and device thereof:https://patents.google.com/patent/JPH11171501A/enCatalyst for producing hydrogen and oxygen and method for producing hydrogen and oxygen by thermal decomposition of waterhttps://patents.google.com/patent/JP3939389B2/en
Hydrogen gas generating method:https://patents.google.com/patent/EP1245531A1/ento be continued..